Biodiesel Sodium Methoxide - Alternative fuel
looking for better alternatives
Probably
one of the most popular catalysts used in creating biodiesel is
sodium methoxide. To create biodiesel, one needs to introduce a
catalyst and an alcohol to the medium. And despite the dangers
and the disadvantages involve in using sodium methoxide, the
compound is still being used today because of the lack of
viable alternatives.
Derived from methoxide which
is an organic salt, sodium methoxide which is also known as
sodium methylate is an initiator of an anionic addition
polymerization with ethylene oxide. Resulting from the process
is the formation of a polyether with high molecular weight.
When used in the production of biodiesel sodium methoxide
transesterifies with methanol the various vegetable oils or
animal fats to create fatty acid methyl esters which are
used.
Sodium methoxide is not a
rare compound. Actually it is manufactured on an industrial
scale. One can easily buy it from a number of chemical
companies but the major world supplier today is the BASF
company.
When used in biodiesel
production, sodium methoxide serves as a powerful base.
Actually, transesterified biodiesel is a common method of
production. It is a known fact that sodium methoxide can
substantially increase produce. One should note, however, that
water is a potent catalyst to stop any reaction that has been
induced by the use of methoxide.
Moreover, methoxide is highly
volatile and the resulting sodium methoxide is highly toxic.
During the process of creating sodium methoxide, lots of
hydrogen and heat are used increasing the dangers involved in
the process. The high toxicity levels of sodium methoxide also
make it very hazardous catalyst to be used in biodiesel
productions.
What the chemical does is
kill human nerve cells before any pain can be felt. When
exposure to methoxide occurs, it is best to rinse the affected
areas with water and ask for medical treatment
immediately.
Another major disadvantage of
using sodium methoxide in biodiesel production is the fact that
the compound needs to be purified from the biodiesel. Not doing
so can cause a lot of problems for the end
consumers.
First off, unwashed biodiesel
will never meet the standards of ASTM (American Society of
Testing and Materials).
Second, when the biodiesel
left unwashed some alcohol, sodium hydroxide, and soap may
remain in the fuel itself. These elements can easily cause
biological growth when the fuel degrades which can ruin the
engine or its parts.
Another reason why unwashed
biodiesel is not advisable is that having unreacted methanol in
the biodiesel fuel can result
in fire or explosion aside from causing corrosion to some of
the engine's parts. In particular, unfiltered sodium methoxide
might also cause corrosion of other engine
components.
There are a number of ways to
clean the biodiesel of impurities. Most of the time, impurities
like unreacted sodium methoxide settle out into the glycerol
layer. However, the actual process of removing them from the
fuel is tedious and time consuming. Most manufacturers of
biodiesel wash the fuel either through agitation washing, mist
washing or and bubble washing.
Regardless of techniques, the
basic element in washing biodiesel is mixing it with water. By
adding water to the fuel, the excess alcohol, sodium hydroxide,
and soap are absorbed and later on the water and the impurities
in it can be drained from the bottom of the container. However,
it does take a number of water cycles to totally remove the
impurities from the fuel. Also, it might take the same amount
of water as biodiesel to wash off those impurities.
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