The need for solid
catalysts in biofuel production
It is unfortunate that the world has to
cope with the various kinds of pollution that man himself has
caused. From water to land pollutions, mother Earth seems to be
helpless. It is a good thing that man has realized his folly
and is trying to make amends by creating pollut ion prevention
technologies and by cleaning up the environment. Among the most
important inventions, innovation or discovery is biodiesel
fuel.
Biodiesel
fuel is beneficial to the environment because of having
cleaner emissions compared to coal oil and conventional
petroleum based fuel. Biodiesel fuel is generally made through
transesterificating oils such as vegetable oils and waste
vegetable oils. The process involves using a catalyst and an
alcohol and applying them to the medium. The most commonly used
catalyst for biodiesel production is sodium hydroxide or
potassium hydroxide.
In creating the actual fuel, the most
common method used is the base catalyzed production method.
With this method alcohol and the catalyst are mixed together,
with the catalyst being dissolved in the alcohol. The oil or
fat is then added to the alcohol/catalyst mix and then just
wait for them components to react with each other. There are
times that the mix is kept just above the boiling point of the
alcohol to help speed up the reaction.
Most of the time, reaction speed varies
from 1 to 8 hours. Once the reaction has been completed there
is still a need to post-process the resulting biodiesel fuel
since it has impurities. Most of the time the biodiesel fuel
will contain excess methanol, glycerin or parts of the catalyst
what was used in the process.
There are a number of ways to remove
these impurities from the biodiesel fuel. Excess alcohol can be
by using a flash evaporation process or by distillation.
Glycerin, on the other hand can be neutralized though the use
of acids and are stored as crude glycerin.
When the biodidesel fuel is separated
from the excess glycerin, the fuel itself can be further
purified by washing the fuel with water. Once the fuel has been
purified, the end produce is a clear amber-yellow liquid that
looks pretty much the same as petroleum based
diesel.
This is one of the basic disadvantages of
using liquid kinds of catalyst in biodiesel production. The
fact that residual elements of the catalyst are needed to be
removed from the biodiesel fuel after the process has been
achieved. Biodiesel created by using such catalysts require
manufacturers to post process the biodiesel
fuel.
This means having the biodiesel undergo treatment to remove the
alkaline components of the fuel. This additional filtration or
refining process adds to the already high manufacturing costs.
But manufacturers have no choice but to accept the higher costs
of production.
Because of such disadvantages, not
considering the inherent problems involve in using sodium methoxide, has
prompted researches and studies on the area of finding the
right catalysts for biodiesel production.
And among the paths of research that are
being considered in biodiesel production, the attempt to look
for solid types of catalysts is being undertaken by researchers
and scientists alike. Solid catalysts have a major advantage:
they can be separated easily from the biodiesel fuel and thus
can be removed quickly. By adapting an easier way to remove the
residues, the whole process of production is, therefore, less
expensive than before.
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